A method of examining refractive and dispersive powers, by prismatic reflection. - Rare Book Insider
book (2)

Wollaston, William Hyde.

A method of examining refractive and dispersive powers, by prismatic reflection.

(London ): 1802
  • $594
(29 x 23,5 cm). SS. 365-386. Mit 1 Kupfertafel. Moderne Broschur, unbeschnitten. (Aus: Philosophical Transactions of the Royal Society). Erste Ausgabe. - "In 1802 Wollaston introduced the important method of determining refractive indices by total internal reflection. The alternative method of minimum deviation, however, continued to be used in the early part of the century. His observations on an impure spectrum led him to conclude that there were only four colors in the solar spectrum. This influenced Thomas Young, who was led by it to alter his own theory of color vision. At the same time Wollaston discovered the dark lines in the solar spectrum, later to be known as Fraunhofer lines. Also in 1802 he presented convincing experimental support for Huygens' wave theory. Using the technique he had invented, he measured the refractive index of Iceland spar in different directions and showed that for different planes of incidence the extraordinary ray was refracted exactly as Huygens' theory predicted. He did not commit himself, however, to a firm statement of belief in the wave theory. This later brought Wollaston charges of timidity and undue caution; but there was no reason why he should have gone further, particularly since Young's impressive evidence had not yet appeared" (DSB). - Gering fleckig, sonst gut erhalten. - DSB 14, 486
More from Antiquariat Gerhard Gruber
book (2)

Beiträge zur Theorie der Affinität und Valenz.

Werner, Alfred. (20,5 x 13 cm). (2) 41 S. Mit 18 Abbildungen. Broschur mit altem Material. (Sonderdruck aus: Vierteljahrschrift der Züricher naturf. Ges.). Erste Ausgabe seiner bahnbrechenden und sehr seltenen Habilitationsschrift. - "Werner spent the next two years working on his Habilitationsschrift, 'Beiträge zur Theorie der Affinität und Valenz,' in which he chose to attack the supreme patriarch of structural organic chemistry, August Kekulé. In this work Werner attempted to replace Kekulé's concept of rigidly directed valences with his own more flexible approach, in which he viewed affinity as a variously divisible, attractive force emanating from the center of an atom and acting equally in all directions. By the use of this new concept and without assuming directed valences, Werner was able to derive the accepted van't Hoff configurational formulas. Although this important paper contains the seeds that later flowered in the primary valence (Hauptvalenz) and secondary valence (Nebenvalenz) of the coordination theory, it deals exclusively with organic compounds. Unfortunately, it was published in a rather obscure journal of limited circulation, where it elicited little notice until brought to the attention of the scientific world in 1904 by a discussion of its concept in Werner's first textbook" (DSB). - Werner (1866-1919), Professor für Chemie in Zürich, begründet mit seinen Arbeiten über die Bindung der Atome in Molekülen die Stereochemie der anorganischen Verbindungen und erhält 1913 dafür den Nobelpreis für Chemie. - Titel gebräunt und gestempelt, sonst gut erhalten. - DSB 14, 264; Kauffman A7
  • $928